Dec 19, 2019 intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Pdf the influence of material factors on the intergranular stress corrosion cracking igscc susceptibility of austenitic stainless steels under. In this chapter, the conditions for the occurrence of scc are first introduced. The precipitation of chromium carbides consumed the alloying element chromium from a narrow band along the grain boundary and this makes the zone anodic to the unaffected grains. In areas where corrosion is a concern, stainless steel. Intergranular corrosion forms along the grain structure of metal. Cracking of stainless steel nozzle sleeve metallurgical. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. This paper reports that the results indicate that the mechanisms of intergranular stress corrosion cracking and transgranular stress corrosion cracking of cu30 au are identical. Severe environments from a corrosive point of view are high concentrations of hydrochloric or hydrofluoric acid in which the corrosion. Intergranular corrosion mechanism of slightlysensitized. Metals like stainless steels and aluminum contain elements such as niobium and chromium, often integrated because of their natural corrosion resistance.
Intergranular corrosion can occur in many alloys systems such as stainless steel. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. In the presence of tensile stress, cracking may occur along grain boundaries and this. Mar 28, 2016 intermetallic compound such as mg5 al8,formation at the grain boundaries form a galvanic cell with a alloy matrix and in chloride environment severe intergranular type of corrosion occur. Knifeline attack impacts steels stabilized by niobium, such as 347 stainless steel. Stainless steel requires a supply of oxygen to make sure that the passive layer can form on the. Duplex stainless steels possess superior resistance to both transgranular and intergranular stress corrosion cracking. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel.
Pdf intergranular cracking of aisi 316ng stainless steel in. Brittleness results, causing the metal to crack near the weld. The sensitization heat treatment range of austenitic stainless steel is 450 c 850 c. You can avoid pitting corrosion by ensuring that stainless steel does not come into prolonged contact with harmful chemicals or by choosing a grade of steel which is more resistant to attack. Influence of chromium depletion on intergranular stress. Austenitic stainless steels such as types 304 and 316 are susceptible to intergranular corrosion igc and intergranular stress corrosion cracking igscc when heat treated at temperatures in the range of 450sup 0 to 850sup 0c. The problem of corrosion the special case of stainless steel types of corrosion general corrosion localized corrosion intergranular corrosion pitting corrosion crevice corrosion galvanic corrosion stress corrosion cracking factors affecting corrosion corrosion testing intergranular corrosion pitting and crevice corrosion stress corrosion cracking.
For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Uniform corrosion or general corrosion occurs on stainless steel in acid environments or hot alkaline solutions. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Intergranular corrosion of stainless steel often occurs after an incorrect heat treatment, and the heat treatment that causes the intergranular corrosion tendency of stainless steel is called sensitization heat treatment. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. The bolts exhibited corrosion predominantly on the head of the bolt around the set screw, underneath the head of the bolt, and in the threads. Sensitization, intergranular attack, stress corrosion. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8.
This form of corrosion occurs at high temperature in the presence of chloride ions and oxygen. Jul 25, 2017 intergranular corrosion forms along the grain structure of metal. Metals like stainless steels and aluminum contain elements such as niobium and chromium, often integrated because of their natural corrosion. The results indicate that the electrochemical contribution to the scc of cu30au in 0. Intergranular corrosion of aisi 316l steel request pdf. This causes the steel or alloy to become susceptible to intergranular corrosion or intergranular stress corrosion cracking. Intergranular stress corrosion cracking has occurred in bwr environments in nonsensitised, coldworked austenitic stainless steel materials. Corrosion types and prevention stainless steel electrical. These tests are often run as a qualification test to ensure each batch of stainless steel is properly prepared.
Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Grain boundaries that are rich in chromium elements will precipitate lead. L sensitization and intergranular corrosion of austen itic stainless steel steels become stainless, i. Gooch introduction although austenitic stainless steels.
For this reason, a postweld heat treatment is needed before reinstalling stainless steel parts that have been welded. Titanium, niobium, and their carbides dissolve in steel at very high temperatures. The intergranular stress corrosion cracking igscc growth behavior of austenitic stainless steels ss in hydrogenated hightemperature water were studied using compact tension specimens. Chloride stress corrosion cracking in austenitic stainless steel. These specimens will have low corrosion rates in certain corrosion.
It is also called weld decay since it usually happens during welding process when the. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Intergranular corrosion stainless steel tubing manufacturer. In nickel alloys and austenitic stainless steels, where chromium is added for corrosion resistance, the mechanism involved. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Paper presented at stainless steel world 2005 conference, maastricht, the netherlands, 810 november 2005. Induction heating stress improvement ihsi has been shown to be the most effective means of dealing with intergranular stress corrosion cracking igscc in the weldments of austenitic stainless. Intergranular stress corrosion cracking igscc of structural materials such as type 304 stainless steel 304ss and type 316l stainless steel. However, with modern steel making methods, it has become possible.
The main form of corrosion of stainless steel corrosion surface corrosion, pitting corrosion, crevice corrosion and stress corrosion. Intergranular attack in welded stresscorrosion resistant. The degree of sensitization dos of austenitic stainless steel aisi 316l to intergranular corrosion igc was determined by means of electrolytic etching in oxalic acid and electrochemical. Reheating a welded component during multipass welding is a common cause of this problem. A minimum amount in the vicinity of 12 percent chromium by weight is required for a steel to exhibit stainless. This occurs at temperatures between about 450850 c. Intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo. Pdf intergranular cracking of aisi 316ng stainless steel. However, a new type of cracking of the steel has been reported on both laboratory tests 2, 3 and the actual commercial pipeline. These tests are often run as a qualification test to ensure each batch of stainless steel. Pdf intergranular stress corrosion cracking behavior of. Intergranular corrosion of stainless steels figure 1.
Intergranular corrosion and intergranular stress corrosion cracking are the two. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. The astm a 262 tests can determine if the proper heat treatment was performed or if the alloys are in danger of intergranular corrosion occurring in use. Paper presented at stainless steel world 2005 conference, maastricht, the. Intergranular stress corrosion cracking scc of pipelines has been known to cause. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. If the carbon level in the steel is too high, chromium can combine with carbon to form chromium carbide. It results from chromium depletion in the vicinity of carbides precipitated at grain boundaries. Stainless steels and weld decay sensitization are the best examples of intergranular corrosion. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. To understand intergranular corrosion testing or intergranular attack commonly abbreviated as igc or iga, it is important to understand what causes the process to occur. The combination of stress and igc, for some alloysenvironment systems will cause intergranular stress corrosion cracking igscc zhou and zuo, 2015.
Inter granular corrosion can be detected by ultrasonic and eddy current methods. Corrosion and corrosion properties of stainless steels. Dec 23, 2018 corrosion then proceeds along the affected grain boundary and may cause grains to dislodge due to the boundary deterioration. Postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Intergranular stress corrosion cracking igscc and transgranular stress corrosion cracking tgscc were found in sensitized 304 stainless steel and only tgscc was found at solution annealed 304 and. Igscc of bwr low carbon and stabilized stainless steels, late 1980s. Stainless steel corrosion pitting corrosion crevice. Intermetallic compound such as mg5 al8,formation at the grain boundaries form a galvanic cell with a alloy matrix and in chloride environment severe intergranular type of corrosion occur. Austenitic stainless steels such as types 304 and 316 are susceptible to intergranular corrosion igc and intergranular stress corrosion cracking igscc when heat treated at temperatures in the range of.
It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries. Chromium, nickel and molybdenum gives greater corrosion. Postweld heat treatment to avoid stress corrosion cracking. Intergranular attack in welded stress corrosion resistant stainless steels satisfactory stress corrosion resistance is obtained using arc welding and, depending on the base metal, type 376. In areas where corrosion is a concern, stainless steel products offer value and protection against these threats. The exact degree to which any of these alloys is resistant to any form of corrosion. Direct correlations are made between the extent of chromium depletion at grain boundaries and intergranular stress corrosion cracking igscc of 304 stainless steel during slowstrainrate ssr tensile tests in 288 c airsaturated water. Chloride scc is intergranular corrosion and occurs in austenitic stainless steel. Intergranular attack is also a quite rare form of corrosion. The intergranular stress corrosion cracking of sensitized 304 stainless steel in na2s2o3 solutionwas detected by electrochemical noise en. Intergranular stress corrosion cracking initiation model of austenite. Chloride stress corrosion cracking stainless steel corrosion corrosion of piping corrosion process surface coatings for corrosion corrosion resistant material bi metallic corrosion.
This type of corrosion was previously a potential risk for stainless steel because of its high carbon content. The photos above show the microstructure of a type 304 stainless steel. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Intergranular stress corrosion cracking resistance of. Characterization of intergranular stress corrosion cracking of 304. This paper evaluates the resistance to intergranular stress corrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion. Analysis of corroded stainless steel bolts summary. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. Observations of intergranular stress corrosion cracking in a. Transgranular stress corrosion cracking an overview.
Intergranular stress corrosion cracking of austenitic. For this reason, a postweld heat treatment is needed before reinstalling stainless steel parts. Jul 18, 2008 nondestructive threedimensional mapping of grain shape, crystallographic orientation, and grain boundary geometry by diffraction contrast tomography dct provides opportunities for the study of the interaction between intergranular stress corrosion cracking and microstructure. The sensitization heat treatment range of austenitic stainless steel. Galvanic corrosion intergranular corrosion intergranular corrosion of stainless steel tubes corrosion resistant stainless steel tube corrosion resistance of. In austenitic stainless steels, titanium or niobium can react with carbon to form carbides in the heat affected zone haz causing a specific type of intergranular corrosion known as knifeline attack. Intergranular stress corrosion cracking of welded steel twi. Intergranular corrosion of 304 stainless steel during the fabrication of stainless steel components or structures it is possible to degrade the corrosion resistance.
Cracks initiated at intergranular corrosion penetrations propagating by corrosion assisted fatigue. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The following discussions present the metallurgical conditions and causes leading to sensitization of austenitic stainless steel and. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. In aqueous environments, metals may be exposed to not only uniform corrosion, but also to various types of local corrosion including pitting, crevice, intergranular, stress, and galvanic corrosion. Intergranular corrosion can occur in many alloys systems such as stainless steel, nickel base and aluminum base alloys. Intergranular corrosion igc can seriously weaken the bonding force between crystal grains and the mechanical strength of metals and alloys would be markedly damaged due to igc. It is believed that this occurs because the chromium content immediately adjacent to the carbide may be below that required for the stainless steel. A stress corrosion crack was grown through a volume of sensitized austenitic stainless steel mapped with dct and. Mti received five stainless steel bolts from a marine environment. Failure analysis of corrosion on stainless steel fasteners.
In austenitic stainless steels, titanium or niobium can react with carbon to form carbides in the heat affected zone haz causing a specific type of intergranular corrosion. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Intergranular corrosion pitting corrosion crevice corrosion galvanic corrosion stress corrosion cracking. Understanding of the mechanism of intergranular stress. Grain boundary precipitation, notably chromium carbides in stainless steels, is a well recognized and accepted mechanism of intergranular corrosion. Different kinds of corrosion on stainless steel montanstahl. Corrosion is galvanic corrosion of metal surfaces all media. Fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. At some cooling regimes depending on the rate of cooling. Astm a262 intergranular corrosion testing and analysis. Intergranular corrosion facts and how to reduce the risk. Feb 06, 2011 intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the bulk of t he grains remain largely unaffected igc is associated. Variation of slow strain rate test fracture mode of type 304l stainless steel.
Intergranular corrosion occurs in certain grades of stainless steel when the steel is heated, as in welding. Chromium, nickel and molybdenum gives greater corrosion resistance. Another related kind of intergranular corrosion is termed knifeline attack kla. Postweld heat treatment to avoid stress corrosion cracking twi. Intergranular stress corrosion cracking an overview. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking.